Inverse Jahn-Teller Transition in Bimetallic Oxalates

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Inverse Jahn-Teller transition in bimetallic oxalates.

Because of the competition between the spin-orbit coupling and the Jahn-Teller (JT) energies in Fe(II)Fe(III) bimetallic oxalates, we theoretically predict that an undistorted phase with C3 symmetry about each Fe site may be recovered at low temperatures. Both lower and upper JT transitions bracketing the ferrimagnetic transition temperature Tc are predicted for compounds that exhibit magnetic ...

متن کامل

Spin waves in antiferromagnetically coupled bimetallic oxalates.

Bimetallic oxalates are molecule-based magnets with transition-metal ions M(II) and M(')(III) arranged on an open honeycomb lattice. Performing a Holstein-Primakoff expansion, we obtain the spin-wave spectrum of antiferromagnetically coupled bimetallic oxalates as a function of the crystal-field angular momentum L(2) and L(3) on the M(II) and M(')(III) sites. Our results are applied to the Fe(I...

متن کامل

Jahn - Teller Effect in Diamond - like Carbon

The Jahn-Teller effect used semi-theoretically to analyse UV-visible spectra of the diamond like-carbon films on Si substrates. By deconvolution of UV-visible absorption spectra of the typical films, different absorption lines found. For each sample, six lines which were related to V • by Jahn-Teller effect are distinguished. Our theoretical approach based on distortion of the V • as the conseq...

متن کامل

Polarons and Solitons in Jahn-Teller Systems

Using a semiclassical continuum model of an electron in a deformable molecular crystal, some properties of multicomponent generalizations of the polaron–“vector polarons”– are elucidated. Analytical solutions for the case of two electronic bands coupled to two vibrational modes are given in detail. Within the model considered, the vector polaron can be classified by its wavefunction into severa...

متن کامل

Magnetic anisotropy in the Fe(II)Fe(III) bimetallic oxalates

Bimetallic oxalates are layered molecule-based magnets with transition metals M II and M III coupled by oxalate molecules ox=C2O4 in an open honeycomb structure. Among the most interesting molecule-based magnets, Fe II Fe III bimetallic compounds with spins S=2 and S =5 /2 ferrimagnetically order at a transition temperature Tc that ranges from 30 to 48 K, depending on the organic cation between...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Physical Review Letters

سال: 2008

ISSN: 0031-9007,1079-7114

DOI: 10.1103/physrevlett.101.116402